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Dual Nature

01
CONCEPT

Discharge, Cathode Rays & Thomson

In one line
At low pressure and high voltage a gas conducts, and the cathode gives out fast electrons called cathode rays.
DISCHARGE

25.1.1 Discharge through gases

  1. At normal pressure a gas is a poor conductor; about 30 kV is needed for a spark across a few cm of air.
  2. The tube is about 30 cm to 40 cm long and 4 cm in diameter.
  3. At low pressure the mean free path is larger, so electrons gain more KE between collisions.
  4. Fast electrons hit neutral atoms and ionise them.
  5. Coloured glow: charged particles from the cathode collide with gas atoms, and the excited atoms give out light.
gashigh voltage−+manometervacuum pump
Discharge tube with a vacuum pump
Pressure (mm of Hg)What is seen
10zig-zag spark, cracking sound
4glow at the electrodes only (dark discharge)
below 4positive column fills the tube
1.65negative glow; Faraday’s dark space
0.8Crooke’s dark space, cathode glow
0.05column splits into striations
0.01cathode rays; the glass glows
10−4no discharge
GasAirH2N2Cl2CO2Neon
Colourpurple redblueredgreenbluish whitedark red
CATHODE RAYS

25.1.2 Properties of cathode rays

  1. Streams of fast electrons, produced at about 10−2 mm of Hg.
  2. They travel in straight lines and leave the cathode normally.
  3. They exert force, produce heat and cause fluorescence.
  4. They are deflected by electric and magnetic fields.
  5. They ionise gases and pass through thin metal foils.
  6. Speed: from 130 to 110 of the speed of light.
  7. On a heavy metal target they produce X-rays.
EMISSION

25.1.3 Ways of getting electrons out

  1. Thermionic: by heating; thermions are electrons.
  2. Photoelectric: by light. Secondary: by fast electrons hitting a surface.
  3. An oxide coating lowers the work function, so a coated filament emits at a lower temperature.
  4. X-ray emission gives out photons, not electrons.
THOMSON

25.1.4 Thomson’s experiment

  1. Crossed E and B act on the beam.
  2. Fields are adjusted so that the beam reaches P with no deflection.
+−⊗ BPP′P″XCAV (anode voltage)fluorescent screen
Crossed fields act on the electron beam
eE = evB ⇒ v = EB
  1. Anode voltage gives the speed.
eV = ½mv² ⇒ v = √(2eVm)
em = v²2V = E²2VB²
  1. em = 1.77 × 1011 Ckg, far above that of the proton.
  2. It does not depend on the gas in the tube.
  3. At large speed the mass grows, m = m0 ÷ √(1 − v²c²), so em falls.
  4. Switch off E, keep B: the beam moves in a circle.
DEFLECTION

25.1.5 Deflection in an electric field

+−Eyle⁻v
The path is a parabola inside the plates
y = ½(eEm)l²v²
MILLIKAN

25.1.6 Millikan’s oil drop experiment

+−V, doil dropsqEmg
A balanced drop stays at rest
balanced drop: qE = mg,  E = Vd
  1. Charge on a drop is always a whole number times e.
q = ne,  e = 1.6 × 10−19 C
JEE · NEET

Corner

Millikan: charge on the drop
q = 6πη(v1 + v2)dV [9ηv12g(ρ − σ)]½
  1. η = viscosity of air, d = gap between the plates, V = voltage.
  2. v1 = terminal speed with no field; v2 = terminal speed with the field on.
  3. ρ = density of oil, σ = density of air.
Positive rays
+cathode (holes)anode+++positive rays
Positive ions pass through the holes in the cathode
  1. Made at about 10−3 mm of Hg when fast electrons ionise gas atoms.
  2. They carry a range of speeds, much smaller than cathode rays.
  3. qm depends on the gas in the tube; it is largest for hydrogen.
  4. Deflection in E and B is small compared with cathode rays.
  5. Their charge is an integral multiple of e.
  6. They cause more ionisation than cathode rays.
  7. Their discovery helped in discovering isotopes.
Thomson’s mass spectrograph
  1. E and B are parallel to each other, and both perpendicular to v.
  2. Electric deflection is along y; magnetic deflection is along z.
y = qELDmv²  ·  z = qBLDmv
z² = k(qm)y,  k = B²LDE
zyOsmallqmlargeqm
One parabola for each value of qm
  1. Ions of the same qm lie on one parabola; faster ions lie nearer the origin.
  2. The number of parabolas gives the number of isotopes.
Bainbridge mass spectrograph
+−+qvelocityselectorB′plate2r₁m₂m₁
Velocity selector followed by the analysing field
  1. Velocity selector (E ⟂ B) lets through only v = EB.
  2. In the analysing field B′ the ions move on circles.
r = mEqBB′  ·  r1r2 = m1m2
separation of traces = 2v(m2 − m1)qB′
Practise PYQs on this topicCathode Rays, Thomson's Experiment & Gas Discharge · 12 questions with solutions
02
CONCEPT

Photons

In one line
Light travels as packets of energy called photons; each has energy hν, and its number decides the power.
ENERGY

25.2.1 Energy and momentum of a photon

E = hν = hcλ
E (in eV) = 12400λ (in Å) = 1240λ (in nm)
  1. h = 6.63 × 10−34 J s; 1 eV = 1.6 × 10−19 J.
  2. Moves at speed c in vacuum.
  3. Rest mass is zero; it is uncharged, so E and B do not deflect it.
p = Ec = hνc = hλ
effective mass m = Ec² = hcλ
  1. Equal momentum ⇒ equal wavelength ⇒ equal energy.
  2. Entering glass: frequency and energy stay the same; speed and wavelength fall.
NUMBER

25.2.2 Number of photons per second

n = PE = Phν = Pλhc
  1. For the same power, longer wavelength ⇒ more photons per second.
  2. If only a fraction η of the power becomes light, use ηP in place of P.
  3. Monochromatic source in time t: number = nt.
INTENSITY

25.2.3 Intensity

  1. Energy crossing unit area normally per second (W/m²).
I = EAt = PA
point source: I = P4πr² ⇒ I ∝ 1r²
PRESSURE

25.2.4 Radiation pressure and force

absorbingreflecting
A reflected photon changes its momentum twice as much
SurfacePressureForceMomentum given
absorbingIcPcUc
perfect reflector2Ic2Pc2Uc
fraction r reflected(1 + r)Ic(1 + r)Pc(1 + r)Uc
  1. U = total energy falling on the surface; P = power.
  2. Absorbs a part a, reflects a part r: F = Pc(a + 2r).
DUAL NATURE

25.2.5 Wave and particle

Light as a waveLight as a particle
interference, diffraction, polarisationphotoelectric effect, Compton effect
  1. Photoelectric effect cannot be explained by the wave theory.
  2. One experiment shows only one nature at a time.
Practise PYQs on this topicPhotons: Energy, Momentum & Radiation Pressure · 49 questions with solutions
03
CONCEPT

Work Function & Einstein’s Equation

In one line
One photon gives all its energy to one electron: part pulls the electron out, the rest becomes its kinetic energy.
PHOTOELECTRIC

25.3.1 Photoelectric effect

  1. Electrons (photoelectrons) leave a metal when light of suitable frequency falls on it.
  2. Nearly all metals respond to UV; alkali metals (Li, Na, K, Rb, Cs) respond to visible light also.
  3. Emission is instant: there is no time lag.
WORK FUNCTION

25.3.2 Work function, threshold frequency and wavelength

  1. Work function W0: minimum energy needed to remove an electron from the metal.
  2. Threshold frequency ν0: minimum frequency for emission.
  3. Threshold wavelength λ0: maximum wavelength for emission.
W0 = hν0 = hcλ0
W0 (in eV) = 12400λ0 (in Å) = 1240λ0 (in nm)
  1. ν < ν0 or λ > λ0: no emission, however bright the light.
  2. Larger W0 ⇒ larger ν0 ⇒ smaller λ0.
  3. For two metals: λ0 ∝ 1W0.
MetalW0 (eV)MetalW0 (eV)
platinum6.4aluminium4.3
gold5.1sodium2.7
copper4.7lithium2.5
silver4.3potassium2.2
nickel5.1cesium1.9
EINSTEIN

25.3.3 Einstein’s photoelectric equation

metalE = hν0 E = hνKE = 0KE = maxbound e⁻
Photon at ν0 just frees the electron; a larger hν gives it KE
hν = W0 + Kmax
Kmax = hν − W0 = h(ν − ν0)
Kmax = hc(1λ − 1λ0)
  1. Kmax is for electrons at the surface.
  2. Electrons from deeper inside lose energy on the way, so emitted electrons have a range of KE from 0 to Kmax.
SPEED

25.3.4 Maximum speed and stopping potential

Kmax = ½mv²max = eV0
vmax = √(2h(ν − ν0)m)
  1. V0 is the stopping (retarding) potential, explained in the next concept.
  2. Kmax in eV has the same number as V0 in volts: V0 = 10 V ⇒ Kmax = 10 eV.
Practise PYQs on this topicPhotoelectric Effect: Einstein's Equation · 175 questions with solutions
04
CONCEPT

Stopping Potential, Maximum Speed & KE Ratios

In one line
The negative plate voltage that just stops the fastest electron is the stopping potential: eV0 = Kmax.
SETUP

25.4.1 Experimental setup

PQe⁻lightrheostatVmA
Light falls on P; electrons travel to Q
  1. P (cathode) and Q (anode) sit in an evacuated tube.
  2. Light on P produces a photoelectric current in the outer circuit.
  3. Q positive: current rises until it saturates.
  4. Q negative: electrons are pushed back and current falls.
  5. At Q = −V0 even the fastest electron is stopped: current = 0.
Kmax = eV0
FORMULAS

25.4.2 Stopping potential formulas

V0 = he(ν − ν0)
V0 = hce(1λ − 1λ0)
V0 (in volt) = 12400λ (in Å) − W0 (in eV)
vmax = √(2hc(λ0 − λ)mλλ0)
TWO LIGHTS

25.4.3 Same metal, two lights

  1. Write Einstein’s equation twice. W0 is the same.
eV1 = hcλ1 − W0,  eV2 = hcλ2 − W0
  1. Subtract to remove W0:
e(V1 − V2) = hc(1λ1 − 1λ2)
  1. In terms of frequency:
h = e(V1 − V2)ν1 − ν2
RATIOS

25.4.4 Ratios of KE and speed

K1K2 = v1²v2² = V1V2 = hν1 − W0hν2 − W0
  1. Kmax is not proportional to ν: doubling ν more than doubles Kmax.
  2. vmax ∝ √(ν − ν0), so it is not proportional to ν either.
  3. Photon energy written in terms of W0: hν = 3W0 ⇒ Kmax = 2W0.
  4. With ν = nν0: Kmax = (n − 1)W0.
Photon energyKmaxV0
2W0W0W0e
3W02W02W0e
5W04W04W0e
  1. Photon from a hydrogen jump: n = 3 to n = 1 gives 12.09 eV; then use Kmax = hν − W0.
Practise PYQs on this topicPhotoelectric Experiment: Intensity, Stopping Potential & Graphs · 87 questions with solutions
05
CONCEPT

Effect of Intensity & Frequency

In one line
Intensity controls how many electrons come out; frequency controls how fast they come out.
INTENSITY

25.5.1 Effect of intensity (frequency fixed)

  1. More intensity ⇒ more photons ⇒ more electrons per second.
  2. Saturation current increases.
  3. Stopping potential and Kmax stay the same.
intensity ∝ photons per second ∝ electrons per second ∝ photocurrent
ViOI2I−V0 ν constant
Same −V0; saturation current ∝ intensity
FREQUENCY

25.5.2 Effect of frequency (intensity fixed)

  1. Higher frequency ⇒ larger V0 and larger Kmax.
  2. Saturation current is taken the same when the intensity is the same.
ViOν₁ν₂ν₂ > ν₁I constant−V₀₁−V₀₂
Same saturation; larger ν gives larger stopping potential
SUMMARY

25.5.3 What depends on what

QuantityIntensityFrequencyMetal
photocurrentyesnono
Kmaxnoyesyes
V0noyesyes
ν0, λ0, W0nonoyes
  1. Kmax and V0 also do not depend on the accelerating voltage or on time.
  2. Accelerating voltage changes the current only until saturation.
BELOW THRESHOLD

25.5.4 Below the threshold

  1. Always check the frequency first.
  2. New ν < ν0 ⇒ photocurrent is zero, even if the intensity is doubled.
  3. At ν = ν0 electrons just get free with zero KE: taken as no current.
  4. Example: 1.5ν0 halved gives 0.75ν0, so current is zero.
WAVE THEORY

25.5.5 Why the wave theory fails

  1. Wave theory says K should grow with intensity: it does not.
  2. Wave theory says any frequency should work if bright enough: there is a threshold.
  3. Wave theory predicts a time lag: emission is instant.
  4. Only the photon picture explains all three.
POINT SOURCE

25.5.6 Moving the source

I ∝ 1d² ⇒ current ∝ 1d²
  1. Move a point source away: current falls.
  2. V0 and Kmax do not change.
Practise PYQs on this topicPhotoelectric Experiment: Intensity, Stopping Potential & Graphs · 87 questions with solutions
06
CONCEPT

Graphs & Photocurrent

In one line
Every photoelectric graph comes from one equation: eV0 = hν − W0. Slope gives h; the intercept gives W0.
V0–ν

25.6.1 Stopping potential against frequency

V0 = (he)ν − W0e
νV₀Oν₀−W₀e
Slope is he; it cuts the axis at ν0
  1. Slope = he; slope × e = h.
  2. X-intercept = ν0.
  3. Y-intercept = −W0e; so W0 = e × (intercept length).
TWO POINTS

25.6.2 Planck’s constant from two points

h = e(V2 − V1)ν2 − ν1
KE–ν

25.6.3 Maximum KE against frequency

Kmax = hν − W0
νKOν₀−W₀slope = h
Same shape; the slope is now h
  1. Slope = h, for every metal.
  2. X-intercept = ν0; Y-intercept = −W0.
  3. The slope does not depend on the metal or on the intensity.
TWO METALS

25.6.4 Two different metals

νV₀OABν₀Aν₀B
Parallel lines: same slope, different ν0
  1. Lines are parallel for all metals.
  2. The line further to the right has the larger ν0, so the larger work function.
  3. The ratio of slopes for any two metals is 1 : 1.
i–V

25.6.5 Reading current against voltage

  1. Where the curve meets the negative axis: −V0, which tells the frequency.
  2. Height of the flat part: saturation current, which tells the intensity.
  3. Same foot ⇒ same frequency. Same height ⇒ same intensity.
  1. Current against intensity: straight line through O. V0 against intensity: flat line.
NUMERICALS

25.6.6 Photocurrent numericals

photons per second on area A: n = IAhν
photocurrent i = ne e,  ne = ηn
  1. η = fraction of photons that free an electron (quantum efficiency).
  2. Point source at d: I ∝ 1d², so the electrons per second change by the same factor.
Practise PYQs on this topicPhotoelectric Experiment: Intensity, Stopping Potential & Graphs · 87 questions with solutions
07
CONCEPT

de Broglie Wavelength: Momentum, KE & Voltage

In one line
Every moving particle has a wave with it, of wavelength λ = hp.
FORMULA

25.7.1 de Broglie wavelength

λ = hp = hmv = h√(2mE)
  1. E = kinetic energy of the particle.
  2. λ ∝ 1p ∝ 1v ∝ 1√E.
Sameλ then depends on
momentumsame λ for all
speedλ ∝ 1m
kinetic energyλ ∝ 1√m
voltageλ ∝ 1√(mq)
CHANGES

25.7.2 KE changes

  1. KE × 4 ⇒ λ becomes half.
  2. KE × 16 ⇒ λ becomes one fourth: a 75% decrease.
  3. To make λ half, KE must become 4 times, so add 3 times the old KE.
λ1λ2 = √(E2E1)
VOLTAGE

25.7.3 Charged particle through a voltage

E = ½mv² = qV
λ = h√(2mqV)
Particleλ (in Å)
electron12.27√V
proton0.286√V
deuteron0.202√V
α-particle0.101√V
  1. V in volts. Same particle: λ1λ2 = √(V2V1).
GRAPH

25.7.4 λ against voltage

λOlighterheavier1√V
Straight lines through the origin
  1. Slope = h ÷ √(2mq).
  2. For the same charge: smaller slope ⇒ larger mass.
COMPARE

25.7.5 Comparing particles

  1. α-particle: m = 4mp, q = 2e.
same V: λpλα = √(mαqαmpqp) = 2√2
same λ: VαVp = mpqpmαqα = 18
NATURE

25.7.6 Nature of matter waves

  1. Tell the probability of finding the particle.
  2. Not electromagnetic and not mechanical.
  3. Exist for charged and uncharged moving particles alike.
Practise PYQs on this topicMatter Waves: de Broglie Wavelength · 151 questions with solutions
08
CONCEPT

Thermal Particles; Photon against Electron

In one line
Temperature gives a particle its KE; a photon and an electron with the same λ have the same momentum but different energy.
THERMAL

25.8.1 Thermal neutrons and gas molecules

  1. Thermal neutron: E = kT.
  2. Gas molecule at rms speed: E = (32)kT.
  3. k = 1.38 × 10−23 JK; T in kelvin.
neutron: λ = h√(2mkT) = 30.83√T Å
gas molecule: λ = h√(3mkT)
λ1λ2 = √(m2T2m1T1)
  1. Change °C to kelvin first.
  2. Same particle, T × 4 ⇒ λ becomes half: 27°C = 300 K to 927°C = 1200 K.
TWO FORMULAS

25.8.2 Photon and electron formulas

PhotonElectron
λ from energyhcEh√(2mK)
energy from λhcλh²2mλ²
momentumEc√(2mK)
SAME ENERGY

25.8.3 Same energy E

λphλe = cE√(2mE) = √(2mc²E)
λeλph ∝ √E
pphpe = √(E2mc²)
SAME WAVELENGTH

25.8.4 Same wavelength λ

  1. They have the same momentum, not the same energy.
EphKe = 2mcλh = 2cv
  1. If λ is the same and speed v of the electron is much less than c, the photon has much more energy.
LIGHT TO ELECTRON

25.8.5 Photoelectron’s wavelength

  1. Light of wavelength λ falls on a metal; find λe of the fastest electron.
  2. Negligible work function: K = hcλ.
λe = h√(2mK) = √(hλ2mc)
  1. So λe ∝ √λ.
  2. With a work function: find K first, then use the same formula.
K = hc(1λ − 1λ0)
Practise PYQs on this topicMatter Waves: de Broglie Wavelength · 151 questions with solutions
09
CONCEPT

Fields, Bohr Orbits & Collisions

In one line
Find the momentum first in any situation, then write λ = hp.
E FIELD

25.9.1 Electron in an electric field

  1. Force eE acts for time t, so momentum changes by eEt.
  2. Starting from rest: p = eEt.
λ = heEt ⇒ dλdt = −heEt²
  1. Force along v0 (the electron speeds up):
λ = λ01 + (eEt ÷ mv0)
  1. Field perpendicular to v0: speed grows sideways.
p² = (mv0)² + (eEt)²
λ = λ0√(1 + (eEt ÷ mv0)²)
B FIELD

25.9.2 Charge in a magnetic field

  1. Magnetic force does no work: speed stays the same.
  2. So λ does not change, whichever way it is going.
  3. On a circle of radius r: p = qBr.
λ = hqBr
BOHR

25.9.3 Bohr orbits

  1. A stable orbit holds a whole number of waves.
n = 5 shown:five waves fiton the orbit
Standing wave along the orbit
2πr = nλ
  1. r ∝ n² and v ∝ 1n, so λ ∝ n.
  2. First orbit: λ equals the circumference of the orbit, 3.3 Å.
λn = 2πa0n ≈ 3.32n Å
  1. Second excited state means n = 3; third excited state means n = 4.
  2. In a magnetic-field orbit: 2πr = nhqBr, so r ∝ √n.
COLLISIONS

25.9.4 Decays and collisions

  1. Momentum is conserved, so use it first.
  2. Particle at rest breaks into two: momenta are equal and opposite, so λ is equal, whatever the masses.
Perfectly inelasticResult
same direction1λ = 1λ1 + 1λ2
opposite direction1λ = |1λ1 − 1λ2|
at right angles1λ² = 1λ1² + 1λ2²
  1. Elastic head-on, B at rest: vA = (mA − mB)v ÷ (mA + mB), vB = 2mAv ÷ (mA + mB).
  2. Equal masses in the centre of mass frame: each has p = ½|p1 − p2|.
Practise PYQs on this topicOther / Mixed: Atoms & Bohr Links · 11 questions with solutions
10
CONCEPT

Davisson-Germer, Uncertainty, Compton & X-rays

In one line
Electrons diffract like waves, and photons collide like particles. Both natures were shown by experiment.
DAVISSON-GERMER

25.10.1 Davisson and Germer experiment

nickel crystalelectron gundetectorφ
Electron beam falls on a nickel crystal
  1. Verified the wave nature of electrons.
  2. Nickel crystal acts as a diffraction grating.
  3. Current in the filament changes the number of electrons.
  4. Voltage between anode and filament changes their speed.
incident50°V = 54 V:peak at 50°
Scattered intensity has a peak at 50° for 54 V
BRAGG

25.10.2 Checking the wavelength

φDdatomic planes
Bragg planes inside the crystal
2d sin θ = nλ
θ = 180° − φ2
  1. d = 0.91 Å and θ = 65° give λ = 1.65 Å.
  2. de Broglie gives 12.27 ÷ √54 = 1.67 Å: close agreement.
  3. Using the spacing D between surface atoms: D sin φ = λ.
MICROSCOPE

25.10.3 Electron microscope

  1. Resolution is of the order of λ of the electrons.
  2. Electrons have far smaller λ than light, so better resolving power.
  3. Same speed: λ ∝ 1m, so a proton microscope has about 1837 times the resolving power.
UNCERTAINTY

25.10.4 Heisenberg’s uncertainty principle

  1. Position and momentum cannot both be known exactly at once.
Δx Δp ≥ h4π
ΔE Δt ≥ h4π
  1. It explains why no electron exists in the nucleus.
  2. Electrons through a narrow slit spread out like waves: angular width ∝ λa; a greater speed gives a smaller λ and narrower spread.
COMPTON

25.10.5 Compton effect

λincident photonescattered photonλ′recoil electronφ
Photon scattered from an electron at rest
Δλ = λ′ − λ = hm0c(1 − cos φ)
  1. Scattered photon has less energy and a longer wavelength.
  2. Energy and momentum are conserved.
  3. Δλ = 0.0024 nm at φ = 90°; 0.0048 nm at φ = 180°.
  4. Photon momentum hλ: use components to find the recoil angle.
X-RAYS

25.10.6 X-ray cut-off wavelength

  1. An electron through V loses all its KE in one collision: this gives the most energetic photon.
eV = hcλmin ⇒ λmin = 12400V Å
  1. λmin depends only on V, not on the target.
electron of wavelength λ: λmin = 2mcλ²h
JEE · NEET

Corner

Coolidge X-ray tube
FtargetelectronsX-rayshigh V
Electrons from the hot filament hit the target
  1. Filament current controls the intensity (number of electrons).
  2. Voltage controls the quality (penetrating power).
  3. Target: high atomic weight and high melting point (tungsten, molybdenum), set at 45°.
  4. About 98% of the energy becomes heat; only about 2% becomes X-rays.
Properties of X-rays
  1. Electromagnetic waves, λ from 0.1 Å to 100 Å.
  2. Uncharged, so not deflected by E or B; travel at the speed of light.
  3. λγ < λX < λUV.
  4. Ionise gases, affect photographic plates, show diffraction and polarisation.
  5. Lead is the best absorber; hydrogen emits no X-rays.
Hard X-raysSoft X-rays
penetrationmoreless
frequencyabout 1019 Hzabout 1016 Hz
wavelength0.1 Å to 4 Å4 Å to 100 Å
Absorption
I = I0 e−μx
half value thickness x½ = 0.693μ
  1. μ ∝ λ³ ∝ Z⁴.
Continuous X-rays
λIλmin30 kV20 kV10 kV
Higher voltage: smaller λmin and greater intensity
  1. A fast electron slows near a nucleus and gives out a photon (Bremsstrahlung).
  2. All wavelengths above λmin are present.
Characteristic X-rays
Kn = 1Ln = 2Mn = 3Nn = 4KαKβKγLαLβ
K series ends on n = 1; L series ends on n = 2
  1. A fast electron knocks out an inner electron; an outer electron drops into the gap.
  2. The sharp lines depend on the target (Z), not on the voltage.
  3. λKα < λLα < λMα and λKα > λKβ > λKγ.
λIKβKαLαλmin
Sharp peaks on top of the continuous spectrum
Moseley’s law
√ν = a(Z − b)
Z√νOKβKα
Straight line for each series
  1. Screening constant: b = 1 (K series), 7.4 (L series).
  2. It showed that atomic number, not atomic weight, orders the periodic table.
1λ = R(Z − b)²(1n1² − 1n2²)
Kα: ν = 2.47 × 1015(Z − 1)² Hz
λKα = 1216(Z − 1)² Å  ·  EKα = 10.2(Z − 1)² eV
Practise PYQs on this topicDavisson-Germer, Uncertainty, Compton & X-Rays · 24 questions with solutions
EXAM-DAY CARD

Just see this before the exam

Dual Nature
E = hν = hcλ
photon
W0 = hν0
work function
Kmax = hν − W0
Einstein
eV0 = Kmax
stopping potential
λ = hp
de Broglie
λ = 12.27√V Å
electron
FORMULA SHEET

Whole chapter on one page

Cathode rays

v = EB

em = E²2VB²

eV = ½mv²

q = ne

Photon

E (eV) = 12400λ (Å)

p = hλ = Ec

n = Pλhc

absorb: Ic; reflect: 2Ic

Photoelectric

W0 = hν0 = hcλ0

Kmax = h(ν − ν0) = eV0

V0 = hce(1λ − 1λ0)

h = e(V1 − V2)ν1 − ν2

Graphs

V0–ν: slope he

K–ν: slope h

x-intercept: ν0

i ∝ I; V0 free of I

Matter waves

λ = h√(2mE) = h√(2mqV)

electron: 12.27√V Å

neutron: 30.83√T Å

gas: h√(3mkT)

Other

orbit: 2πr = nλ

Δx Δp ≥ h4π

Δλ = hm0c(1 − cos φ)

λmin = 12400V Å

TOP MISTAKES

Avoid these = easy marks

MISTAKE ✗

More intensity gives larger Kmax

Kmax ∝ ν, so double ν gives double K

Using λ = hcE for an electron

Doubling intensity below ν0 gives current

CORRECT ✓

Intensity changes the current only

Kmax = hν − W0: more than double

Electron: λ = h√(2mE)

Below ν0 the current is always zero