01
CONCEPT
Discharge, Cathode Rays & Thomson
In one line
At low pressure and high voltage a gas conducts, and the cathode gives out fast electrons called cathode rays.
At low pressure and high voltage a gas conducts, and the cathode gives out fast electrons called cathode rays.
DISCHARGE
25.1.1 Discharge through gases
- At normal pressure a gas is a poor conductor; about 30 kV is needed for a spark across a few cm of air.
- The tube is about 30 cm to 40 cm long and 4 cm in diameter.
- At low pressure the mean free path is larger, so electrons gain more KE between collisions.
- Fast electrons hit neutral atoms and ionise them.
- Coloured glow: charged particles from the cathode collide with gas atoms, and the excited atoms give out light.
Discharge tube with a vacuum pump
| Pressure (mm of Hg) | What is seen |
|---|---|
| 10 | zig-zag spark, cracking sound |
| 4 | glow at the electrodes only (dark discharge) |
| below 4 | positive column fills the tube |
| 1.65 | negative glow; Faraday’s dark space |
| 0.8 | Crooke’s dark space, cathode glow |
| 0.05 | column splits into striations |
| 0.01 | cathode rays; the glass glows |
| 10−4 | no discharge |
| Gas | Air | H2 | N2 | Cl2 | CO2 | Neon |
|---|---|---|---|---|---|---|
| Colour | purple red | blue | red | green | bluish white | dark red |
CATHODE RAYS
25.1.2 Properties of cathode rays
- Streams of fast electrons, produced at about 10−2 mm of Hg.
- They travel in straight lines and leave the cathode normally.
- They exert force, produce heat and cause fluorescence.
- They are deflected by electric and magnetic fields.
- They ionise gases and pass through thin metal foils.
- Speed: from 130 to 110 of the speed of light.
- On a heavy metal target they produce X-rays.
EMISSION
25.1.3 Ways of getting electrons out
- Thermionic: by heating; thermions are electrons.
- Photoelectric: by light. Secondary: by fast electrons hitting a surface.
- An oxide coating lowers the work function, so a coated filament emits at a lower temperature.
- X-ray emission gives out photons, not electrons.
THOMSON
25.1.4 Thomson’s experiment
- Crossed E and B act on the beam.
- Fields are adjusted so that the beam reaches P with no deflection.
Crossed fields act on the electron beam
- Anode voltage gives the speed.
- em = 1.77 × 1011 Ckg, far above that of the proton.
- It does not depend on the gas in the tube.
- At large speed the mass grows, m = m0 ÷ √(1 − v²c²), so em falls.
- Switch off E, keep B: the beam moves in a circle.
DEFLECTION
25.1.5 Deflection in an electric field
The path is a parabola inside the plates
MILLIKAN
25.1.6 Millikan’s oil drop experiment
A balanced drop stays at rest
- Charge on a drop is always a whole number times e.
JEE · NEET
Corner
Millikan: charge on the drop
- η = viscosity of air, d = gap between the plates, V = voltage.
- v1 = terminal speed with no field; v2 = terminal speed with the field on.
- ρ = density of oil, σ = density of air.
Positive rays
Positive ions pass through the holes in the cathode
- Made at about 10−3 mm of Hg when fast electrons ionise gas atoms.
- They carry a range of speeds, much smaller than cathode rays.
- qm depends on the gas in the tube; it is largest for hydrogen.
- Deflection in E and B is small compared with cathode rays.
- Their charge is an integral multiple of e.
- They cause more ionisation than cathode rays.
- Their discovery helped in discovering isotopes.
Thomson’s mass spectrograph
- E and B are parallel to each other, and both perpendicular to v.
- Electric deflection is along y; magnetic deflection is along z.
One parabola for each value of qm
- Ions of the same qm lie on one parabola; faster ions lie nearer the origin.
- The number of parabolas gives the number of isotopes.
Bainbridge mass spectrograph
Velocity selector followed by the analysing field
- Velocity selector (E ⟂ B) lets through only v = EB.
- In the analysing field B′ the ions move on circles.
02
CONCEPT
Photons
In one line
Light travels as packets of energy called photons; each has energy hν, and its number decides the power.
Light travels as packets of energy called photons; each has energy hν, and its number decides the power.
ENERGY
25.2.1 Energy and momentum of a photon
- h = 6.63 × 10−34 J s; 1 eV = 1.6 × 10−19 J.
- Moves at speed c in vacuum.
- Rest mass is zero; it is uncharged, so E and B do not deflect it.
- Equal momentum ⇒ equal wavelength ⇒ equal energy.
- Entering glass: frequency and energy stay the same; speed and wavelength fall.
NUMBER
25.2.2 Number of photons per second
- For the same power, longer wavelength ⇒ more photons per second.
- If only a fraction η of the power becomes light, use ηP in place of P.
- Monochromatic source in time t: number = nt.
INTENSITY
25.2.3 Intensity
- Energy crossing unit area normally per second (W/m²).
PRESSURE
25.2.4 Radiation pressure and force
A reflected photon changes its momentum twice as much
| Surface | Pressure | Force | Momentum given |
|---|---|---|---|
| absorbing | Ic | Pc | Uc |
| perfect reflector | 2Ic | 2Pc | 2Uc |
| fraction r reflected | (1 + r)Ic | (1 + r)Pc | (1 + r)Uc |
- U = total energy falling on the surface; P = power.
- Absorbs a part a, reflects a part r: F = Pc(a + 2r).
DUAL NATURE
25.2.5 Wave and particle
| Light as a wave | Light as a particle |
|---|---|
| interference, diffraction, polarisation | photoelectric effect, Compton effect |
- Photoelectric effect cannot be explained by the wave theory.
- One experiment shows only one nature at a time.
03
CONCEPT
Work Function & Einstein’s Equation
In one line
One photon gives all its energy to one electron: part pulls the electron out, the rest becomes its kinetic energy.
One photon gives all its energy to one electron: part pulls the electron out, the rest becomes its kinetic energy.
PHOTOELECTRIC
25.3.1 Photoelectric effect
- Electrons (photoelectrons) leave a metal when light of suitable frequency falls on it.
- Nearly all metals respond to UV; alkali metals (Li, Na, K, Rb, Cs) respond to visible light also.
- Emission is instant: there is no time lag.
WORK FUNCTION
25.3.2 Work function, threshold frequency and wavelength
- Work function W0: minimum energy needed to remove an electron from the metal.
- Threshold frequency ν0: minimum frequency for emission.
- Threshold wavelength λ0: maximum wavelength for emission.
- ν < ν0 or λ > λ0: no emission, however bright the light.
- Larger W0 ⇒ larger ν0 ⇒ smaller λ0.
- For two metals: λ0 ∝ 1W0.
| Metal | W0 (eV) | Metal | W0 (eV) |
|---|---|---|---|
| platinum | 6.4 | aluminium | 4.3 |
| gold | 5.1 | sodium | 2.7 |
| copper | 4.7 | lithium | 2.5 |
| silver | 4.3 | potassium | 2.2 |
| nickel | 5.1 | cesium | 1.9 |
EINSTEIN
25.3.3 Einstein’s photoelectric equation
Photon at ν0 just frees the electron; a larger hν gives it KE
- Kmax is for electrons at the surface.
- Electrons from deeper inside lose energy on the way, so emitted electrons have a range of KE from 0 to Kmax.
SPEED
25.3.4 Maximum speed and stopping potential
- V0 is the stopping (retarding) potential, explained in the next concept.
- Kmax in eV has the same number as V0 in volts: V0 = 10 V ⇒ Kmax = 10 eV.
04
CONCEPT
Stopping Potential, Maximum Speed & KE Ratios
In one line
The negative plate voltage that just stops the fastest electron is the stopping potential: eV0 = Kmax.
The negative plate voltage that just stops the fastest electron is the stopping potential: eV0 = Kmax.
SETUP
25.4.1 Experimental setup
Light falls on P; electrons travel to Q
- P (cathode) and Q (anode) sit in an evacuated tube.
- Light on P produces a photoelectric current in the outer circuit.
- Q positive: current rises until it saturates.
- Q negative: electrons are pushed back and current falls.
- At Q = −V0 even the fastest electron is stopped: current = 0.
FORMULAS
25.4.2 Stopping potential formulas
TWO LIGHTS
25.4.3 Same metal, two lights
- Write Einstein’s equation twice. W0 is the same.
- Subtract to remove W0:
- In terms of frequency:
RATIOS
25.4.4 Ratios of KE and speed
- Kmax is not proportional to ν: doubling ν more than doubles Kmax.
- vmax ∝ √(ν − ν0), so it is not proportional to ν either.
- Photon energy written in terms of W0: hν = 3W0 ⇒ Kmax = 2W0.
- With ν = nν0: Kmax = (n − 1)W0.
| Photon energy | Kmax | V0 |
|---|---|---|
| 2W0 | W0 | W0e |
| 3W0 | 2W0 | 2W0e |
| 5W0 | 4W0 | 4W0e |
- Photon from a hydrogen jump: n = 3 to n = 1 gives 12.09 eV; then use Kmax = hν − W0.
05
CONCEPT
Effect of Intensity & Frequency
In one line
Intensity controls how many electrons come out; frequency controls how fast they come out.
Intensity controls how many electrons come out; frequency controls how fast they come out.
INTENSITY
25.5.1 Effect of intensity (frequency fixed)
- More intensity ⇒ more photons ⇒ more electrons per second.
- Saturation current increases.
- Stopping potential and Kmax stay the same.
Same −V0; saturation current ∝ intensity
FREQUENCY
25.5.2 Effect of frequency (intensity fixed)
- Higher frequency ⇒ larger V0 and larger Kmax.
- Saturation current is taken the same when the intensity is the same.
Same saturation; larger ν gives larger stopping potential
SUMMARY
25.5.3 What depends on what
| Quantity | Intensity | Frequency | Metal |
|---|---|---|---|
| photocurrent | yes | no | no |
| Kmax | no | yes | yes |
| V0 | no | yes | yes |
| ν0, λ0, W0 | no | no | yes |
- Kmax and V0 also do not depend on the accelerating voltage or on time.
- Accelerating voltage changes the current only until saturation.
BELOW THRESHOLD
25.5.4 Below the threshold
- Always check the frequency first.
- New ν < ν0 ⇒ photocurrent is zero, even if the intensity is doubled.
- At ν = ν0 electrons just get free with zero KE: taken as no current.
- Example: 1.5ν0 halved gives 0.75ν0, so current is zero.
WAVE THEORY
25.5.5 Why the wave theory fails
- Wave theory says K should grow with intensity: it does not.
- Wave theory says any frequency should work if bright enough: there is a threshold.
- Wave theory predicts a time lag: emission is instant.
- Only the photon picture explains all three.
POINT SOURCE
25.5.6 Moving the source
- Move a point source away: current falls.
- V0 and Kmax do not change.
06
CONCEPT
Graphs & Photocurrent
In one line
Every photoelectric graph comes from one equation: eV0 = hν − W0. Slope gives h; the intercept gives W0.
Every photoelectric graph comes from one equation: eV0 = hν − W0. Slope gives h; the intercept gives W0.
V0–ν
25.6.1 Stopping potential against frequency
Slope is he; it cuts the axis at ν0
- Slope = he; slope × e = h.
- X-intercept = ν0.
- Y-intercept = −W0e; so W0 = e × (intercept length).
TWO POINTS
25.6.2 Planck’s constant from two points
KE–ν
25.6.3 Maximum KE against frequency
Same shape; the slope is now h
- Slope = h, for every metal.
- X-intercept = ν0; Y-intercept = −W0.
- The slope does not depend on the metal or on the intensity.
TWO METALS
25.6.4 Two different metals
Parallel lines: same slope, different ν0
- Lines are parallel for all metals.
- The line further to the right has the larger ν0, so the larger work function.
- The ratio of slopes for any two metals is 1 : 1.
i–V
25.6.5 Reading current against voltage
- Where the curve meets the negative axis: −V0, which tells the frequency.
- Height of the flat part: saturation current, which tells the intensity.
- Same foot ⇒ same frequency. Same height ⇒ same intensity.
- Current against intensity: straight line through O. V0 against intensity: flat line.
NUMERICALS
25.6.6 Photocurrent numericals
- η = fraction of photons that free an electron (quantum efficiency).
- Point source at d: I ∝ 1d², so the electrons per second change by the same factor.
07
CONCEPT
de Broglie Wavelength: Momentum, KE & Voltage
In one line
Every moving particle has a wave with it, of wavelength λ = hp.
Every moving particle has a wave with it, of wavelength λ = hp.
FORMULA
25.7.1 de Broglie wavelength
- E = kinetic energy of the particle.
- λ ∝ 1p ∝ 1v ∝ 1√E.
| Same | λ then depends on |
|---|---|
| momentum | same λ for all |
| speed | λ ∝ 1m |
| kinetic energy | λ ∝ 1√m |
| voltage | λ ∝ 1√(mq) |
CHANGES
25.7.2 KE changes
- KE × 4 ⇒ λ becomes half.
- KE × 16 ⇒ λ becomes one fourth: a 75% decrease.
- To make λ half, KE must become 4 times, so add 3 times the old KE.
VOLTAGE
25.7.3 Charged particle through a voltage
| Particle | λ (in Å) |
|---|---|
| electron | 12.27√V |
| proton | 0.286√V |
| deuteron | 0.202√V |
| α-particle | 0.101√V |
- V in volts. Same particle: λ1λ2 = √(V2V1).
GRAPH
25.7.4 λ against voltage
Straight lines through the origin
- Slope = h ÷ √(2mq).
- For the same charge: smaller slope ⇒ larger mass.
COMPARE
25.7.5 Comparing particles
- α-particle: m = 4mp, q = 2e.
NATURE
25.7.6 Nature of matter waves
- Tell the probability of finding the particle.
- Not electromagnetic and not mechanical.
- Exist for charged and uncharged moving particles alike.
08
CONCEPT
Thermal Particles; Photon against Electron
In one line
Temperature gives a particle its KE; a photon and an electron with the same λ have the same momentum but different energy.
Temperature gives a particle its KE; a photon and an electron with the same λ have the same momentum but different energy.
THERMAL
25.8.1 Thermal neutrons and gas molecules
- Thermal neutron: E = kT.
- Gas molecule at rms speed: E = (32)kT.
- k = 1.38 × 10−23 JK; T in kelvin.
- Change °C to kelvin first.
- Same particle, T × 4 ⇒ λ becomes half: 27°C = 300 K to 927°C = 1200 K.
TWO FORMULAS
25.8.2 Photon and electron formulas
| Photon | Electron | |
|---|---|---|
| λ from energy | hcE | h√(2mK) |
| energy from λ | hcλ | h²2mλ² |
| momentum | Ec | √(2mK) |
SAME ENERGY
25.8.3 Same energy E
SAME WAVELENGTH
25.8.4 Same wavelength λ
- They have the same momentum, not the same energy.
- If λ is the same and speed v of the electron is much less than c, the photon has much more energy.
LIGHT TO ELECTRON
25.8.5 Photoelectron’s wavelength
- Light of wavelength λ falls on a metal; find λe of the fastest electron.
- Negligible work function: K = hcλ.
- So λe ∝ √λ.
- With a work function: find K first, then use the same formula.
09
CONCEPT
Fields, Bohr Orbits & Collisions
In one line
Find the momentum first in any situation, then write λ = hp.
Find the momentum first in any situation, then write λ = hp.
E FIELD
25.9.1 Electron in an electric field
- Force eE acts for time t, so momentum changes by eEt.
- Starting from rest: p = eEt.
- Force along v0 (the electron speeds up):
- Field perpendicular to v0: speed grows sideways.
B FIELD
25.9.2 Charge in a magnetic field
- Magnetic force does no work: speed stays the same.
- So λ does not change, whichever way it is going.
- On a circle of radius r: p = qBr.
BOHR
25.9.3 Bohr orbits
- A stable orbit holds a whole number of waves.
Standing wave along the orbit
- r ∝ n² and v ∝ 1n, so λ ∝ n.
- First orbit: λ equals the circumference of the orbit, 3.3 Å.
- Second excited state means n = 3; third excited state means n = 4.
- In a magnetic-field orbit: 2πr = nhqBr, so r ∝ √n.
COLLISIONS
25.9.4 Decays and collisions
- Momentum is conserved, so use it first.
- Particle at rest breaks into two: momenta are equal and opposite, so λ is equal, whatever the masses.
| Perfectly inelastic | Result |
|---|---|
| same direction | 1λ = 1λ1 + 1λ2 |
| opposite direction | 1λ = |1λ1 − 1λ2| |
| at right angles | 1λ² = 1λ1² + 1λ2² |
- Elastic head-on, B at rest: vA = (mA − mB)v ÷ (mA + mB), vB = 2mAv ÷ (mA + mB).
- Equal masses in the centre of mass frame: each has p = ½|p1 − p2|.
10
CONCEPT
Davisson-Germer, Uncertainty, Compton & X-rays
In one line
Electrons diffract like waves, and photons collide like particles. Both natures were shown by experiment.
Electrons diffract like waves, and photons collide like particles. Both natures were shown by experiment.
DAVISSON-GERMER
25.10.1 Davisson and Germer experiment
Electron beam falls on a nickel crystal
- Verified the wave nature of electrons.
- Nickel crystal acts as a diffraction grating.
- Current in the filament changes the number of electrons.
- Voltage between anode and filament changes their speed.
Scattered intensity has a peak at 50° for 54 V
BRAGG
25.10.2 Checking the wavelength
Bragg planes inside the crystal
- d = 0.91 Å and θ = 65° give λ = 1.65 Å.
- de Broglie gives 12.27 ÷ √54 = 1.67 Å: close agreement.
- Using the spacing D between surface atoms: D sin φ = λ.
MICROSCOPE
25.10.3 Electron microscope
- Resolution is of the order of λ of the electrons.
- Electrons have far smaller λ than light, so better resolving power.
- Same speed: λ ∝ 1m, so a proton microscope has about 1837 times the resolving power.
UNCERTAINTY
25.10.4 Heisenberg’s uncertainty principle
- Position and momentum cannot both be known exactly at once.
- It explains why no electron exists in the nucleus.
- Electrons through a narrow slit spread out like waves: angular width ∝ λa; a greater speed gives a smaller λ and narrower spread.
COMPTON
25.10.5 Compton effect
Photon scattered from an electron at rest
- Scattered photon has less energy and a longer wavelength.
- Energy and momentum are conserved.
- Δλ = 0.0024 nm at φ = 90°; 0.0048 nm at φ = 180°.
- Photon momentum hλ: use components to find the recoil angle.
X-RAYS
25.10.6 X-ray cut-off wavelength
- An electron through V loses all its KE in one collision: this gives the most energetic photon.
- λmin depends only on V, not on the target.
JEE · NEET
Corner
Coolidge X-ray tube
Electrons from the hot filament hit the target
- Filament current controls the intensity (number of electrons).
- Voltage controls the quality (penetrating power).
- Target: high atomic weight and high melting point (tungsten, molybdenum), set at 45°.
- About 98% of the energy becomes heat; only about 2% becomes X-rays.
Properties of X-rays
- Electromagnetic waves, λ from 0.1 Å to 100 Å.
- Uncharged, so not deflected by E or B; travel at the speed of light.
- λγ < λX < λUV.
- Ionise gases, affect photographic plates, show diffraction and polarisation.
- Lead is the best absorber; hydrogen emits no X-rays.
| Hard X-rays | Soft X-rays | |
|---|---|---|
| penetration | more | less |
| frequency | about 1019 Hz | about 1016 Hz |
| wavelength | 0.1 Å to 4 Å | 4 Å to 100 Å |
Absorption
- μ ∝ λ³ ∝ Z⁴.
Continuous X-rays
Higher voltage: smaller λmin and greater intensity
- A fast electron slows near a nucleus and gives out a photon (Bremsstrahlung).
- All wavelengths above λmin are present.
Characteristic X-rays
K series ends on n = 1; L series ends on n = 2
- A fast electron knocks out an inner electron; an outer electron drops into the gap.
- The sharp lines depend on the target (Z), not on the voltage.
- λKα < λLα < λMα and λKα > λKβ > λKγ.
Sharp peaks on top of the continuous spectrum
Moseley’s law
Straight line for each series
- Screening constant: b = 1 (K series), 7.4 (L series).
- It showed that atomic number, not atomic weight, orders the periodic table.
EXAM-DAY CARD
Just see this before the exam
E = hν = hcλ
photon
W0 = hν0
work function
Kmax = hν − W0
Einstein
eV0 = Kmax
stopping potential
λ = hp
de Broglie
λ = 12.27√V Å
electron
FORMULA SHEET
Whole chapter on one page
Cathode rays
v = EB
em = E²2VB²
eV = ½mv²
q = ne
Photon
E (eV) = 12400λ (Å)
p = hλ = Ec
n = Pλhc
absorb: Ic; reflect: 2Ic
Photoelectric
W0 = hν0 = hcλ0
Kmax = h(ν − ν0) = eV0
V0 = hce(1λ − 1λ0)
h = e(V1 − V2)ν1 − ν2
Graphs
V0–ν: slope he
K–ν: slope h
x-intercept: ν0
i ∝ I; V0 free of I
Matter waves
λ = h√(2mE) = h√(2mqV)
electron: 12.27√V Å
neutron: 30.83√T Å
gas: h√(3mkT)
Other
orbit: 2πr = nλ
Δx Δp ≥ h4π
Δλ = hm0c(1 − cos φ)
λmin = 12400V Å
TOP MISTAKES
Avoid these = easy marks
MISTAKE ✗
More intensity gives larger Kmax
Kmax ∝ ν, so double ν gives double K
Using λ = hcE for an electron
Doubling intensity below ν0 gives current
CORRECT ✓
Intensity changes the current only
Kmax = hν − W0: more than double
Electron: λ = h√(2mE)
Below ν0 the current is always zero