Energy Bands in Solids
Atoms packed in a solid turn their sharp energy levels into bands. The gap between two bands decides whether the solid conducts.
27.1.1 How bands form
- An isolated atom has sharp, separate energy levels.
- In a crystal, atoms are close and their outer electrons interact.
- By Pauli’s exclusion principle no two electrons can share a state, so each level spreads into a band.
27.1.2 Valence band, conduction band, forbidden gap
- Valence band (VB): band of valence electrons, highest filled band at 0 K. These electrons cannot carry current.
- Conduction band (CB): next higher band. Its electrons are free and carry current.
- Forbidden gap: no electron can stay here.
- Eg falls very slightly as temperature rises.
- Light can lift an electron across only if hν ≥ Eg.
27.1.3 Conductor, insulator, semiconductor
| Conductor | Insulator | Semiconductor | |
|---|---|---|---|
| Bands | VB, CB overlap | VB full, CB empty | VB nearly full, CB nearly empty |
| Eg | zero | > 3 eV (diamond 6 eV) | about 1 eV |
| ρ (Ω m) | 10−8 to 10−2 | 1011 to 1019 | 10−5 to 106 |
| Carriers | free electrons | none | electrons, holes |
| Examples | Cu, Ag, Al | wood, glass, mica | Si, Ge, GaAs |
27.1.4 Band gaps to remember
| Material | Eg |
|---|---|
| Ge | 0.7 eV |
| Si | 1.1 eV |
| GaAs | 1.3 eV |
| Diamond (C) | 6 eV |
- So (Eg)C > (Eg)Si > (Eg)Ge.
- At room temperature a few electrons cross the gap in Si and Ge. Almost none cross in diamond.
- Good conductors have no hole current, because their bands overlap.
Intrinsic & Extrinsic Semiconductors
A pure semiconductor has equal electrons and holes. A tiny impurity makes one of them the majority, and conductivity jumps.
27.2.1 Pure semiconductor
- Si and Ge have 4 valence electrons, held in covalent bonds.
- Heat breaks some bonds. Each broken bond gives one free electron and one hole.
- Conduction due only to breaking of covalent bonds is intrinsic.
- At 0 K no bond is broken, so pure Si behaves as an insulator.
27.2.2 What a hole is
- A hole is a vacancy left by a missing electron.
- It acts like a positive charge +e, though no real positive particle moves.
- A neighbouring electron fills it, so the hole appears to move.
- Holes are slower than electrons: ve > vh.
27.2.3 Adding impurity
- Doping adds about 1 impurity atom per 106 to 108 host atoms.
- Generally it decreases the resistivity sharply.
- A doped semiconductor is called extrinsic, and ne ≠ nh.
27.2.4 Pentavalent impurity
- Dopants (5 valence electrons): P, As, Sb. They are donors.
- Majority carriers: electrons. Minority carriers: holes.
- ne ≫ nh, and the crystal stays electrically neutral.
- Free electrons occupy the donor level, in the gap just below the CB.
27.2.5 Trivalent impurity
- Dopants (3 valence electrons): B, Al, Ga, In. They are acceptors.
- Majority carriers: holes. Minority carriers: electrons.
- nh ≫ ne, and the crystal stays electrically neutral.
- Acceptor level lies in the gap just above the VB.
27.2.6 n-type and p-type
| n-type | p-type | |
|---|---|---|
| Impurity | pentavalent (P, As, Sb) | trivalent (B, Al, In) |
| Majority | electrons | holes |
| Minority | holes | electrons |
| New level | just below CB | just above VB |
| Net charge | zero | zero |
Carrier Concentration, Conductivity & Temperature
The product nenh stays fixed at a given temperature. Heating makes more carriers, so a semiconductor’s resistance falls.
27.3.1 Finding the minority carriers
- Holds at thermal equilibrium, for doped and pure samples.
- More majority carriers means fewer minority carriers.
| Doping | Majority | Minority |
|---|---|---|
| Donor density ND | ne ≈ ND | nh = ni2ND |
| Acceptor density NA | nh ≈ NA | ne = ni2NA |
- Doping of 1 ppm: donor density = 10−6 × atoms per m3.
- Si at 300 K: ni ≈ 1.5 × 1016 m−3. Ge: ni ≈ 2.4 × 1019 m−3.
27.3.2 Two currents in one direction
- Equal concentrations in n-type and p-type: the n-type carries more current, as electrons are more mobile.
27.3.3 Metal against semiconductor
| On heating | Metal | Semiconductor |
|---|---|---|
| Carriers | no real change | increase sharply |
| Collisions | increase | increase |
| Resistance | increases | decreases |
| Conductivity | decreases | increases |
| Temp. coefficient | positive | negative |
- The difference arises from the change in the number of carriers with temperature.
- On cooling, the resistance of Cu falls and that of Si or Ge rises.
- In a circuit with a semiconductor in series, heating raises the current.
- ni rises very quickly with T. Heating adds electrons and holes equally.
- Ge conducts better than Si at room temperature, as its gap is smaller.
Corner
- μ unit: m2V−1s−1.
- Electrons are more mobile than holes: μe > μh.
- n-type: σ ≈ neeμe. p-type: σ ≈ nheμh.
- Current ratio: IeIh = nevenhvh
- Intrinsic: in the middle of the gap.
- n-type: near the conduction band.
- p-type: near the valence band.
- Metal: inside the conduction band.
- Heavier doping moves it further towards that band.
Depletion Layer & Biasing
Joining p and n creates a thin charged layer with a built-in barrier. Forward bias lowers it and reverse bias raises it, so a diode conducts one way.
27.4.1 How the depletion layer forms
- Electrons are plenty in n and holes are plenty in p.
- Carriers diffuse across, because of this concentration difference.
- They leave behind fixed ions: + on the n side, − on the p side.
- This layer of immobile ions has no free carriers: the depletion layer.
27.4.2 Potential barrier
- The two ion layers create a barrier potential VB; the n side is at the higher potential.
- Ge: VB ≈ 0.3 V. Si: VB ≈ 0.7 V.
- VB depends on the material, doping and temperature.
- Width of the layer ≈ 1 μm, and it shrinks with heavier doping.
27.4.3 Diffusion and drift
- Diffusion current: majority carriers, from p to n.
- Drift current: minority carriers pushed by E, from n to p.
- Unbiased: the two are equal, so net current is zero.
- Forward biased: diffusion is larger than drift.
27.4.4 p to +, n to −
- Depletion layer becomes thinner and the barrier falls.
- Current rises sharply above the knee voltage (Ge 0.3 V, Si 0.7 V).
- Resistance is low: about 10 to 25 Ω.
27.4.5 p to −, n to +
- Depletion layer becomes wider and the barrier rises.
- Only a tiny μA current flows, due to minority carriers.
- Resistance is very high: about 105 Ω.
27.4.6 Is it forward biased?
- Compare potentials at the two ends. Arrow side higher than bar side: forward.
- Only the difference matters: +5 V and +3 V across a diode is forward by 2 V if the arrow side is at +5 V.
- Both negative also works: −2 V on the arrow side and −5 V on the bar side is forward.
27.4.7 One-way device
27.4.8 Large reverse voltage
- Current suddenly increases at the breakdown voltage.
- Zener breakdown: heavy doping, strong field breaks bonds directly.
- Avalanche breakdown: light doping, fast carriers knock out more carriers in a chain.
- An ordinary diode is damaged here; a Zener is built for it.
27.4.9 What a diode can and cannot do
- It can rectify, give light (LED), detect light and give solar power.
- It cannot amplify an a.c. signal: that needs a transistor.
- A device that passes 10 mA one way and almost none the other way is a p-n junction.
Corner
- Take ΔV and ΔI from the I-V graph, near the given point.
- Read ΔV over a small ΔI: the curve is steeper at higher V, so rd is smaller there.
- It is not V ÷ I, which gives the static resistance.
- Is = reverse saturation current.
- Forward: current rises exponentially.
- Reverse: I ≈ −Is.
- Equal charge lies on both sides of the junction.
- So the depletion layer goes deeper into the lightly doped side.
- An electron crossing from n to p loses kinetic energy eVB.
Diode Circuits
First decide which diodes are ON and which are OFF. Replace them with a wire or a break, then solve an ordinary circuit.
27.5.1 A one-way switch
| Bias | Resistance | Replace by |
|---|---|---|
| Forward | zero | wire |
| Reverse | infinite | open break |
27.5.2 Solving in three steps
- Trace the current direction from the + of the battery.
- A diode pointing along it is ON. Against it is OFF, so remove that branch.
- Apply Ohm’s law to what is left.
27.5.3 Knee voltage and forward resistance
- A silicon diode drops about 0.7 V when ON. Germanium drops about 0.3 V.
- If a forward resistance is given, add it in series.
- Safe current limit I: minimum R = (E − VD) ÷ I.
- A diode power rating P gives Imax = P ÷ VD.
27.5.4 One diode in each branch
- Check each branch separately.
- The reverse-biased branch carries zero current.
- Two opposite diodes in parallel: one is always ON, so the path always conducts.
27.5.5 Ratio questions
- Redraw the network once with the diode as a wire and once with a break.
- Find RAB both ways, and then the ratio.
27.5.6 Diode between two voltages
- Current through a diode with ends at V1 and V2 needs arrow side higher.
- I = (V1 − V2) ÷ R; it is zero if the bar side is higher.
- With two batteries, use the net emf: adding if they aid, subtracting if they oppose.
Corner
- Work out the diode state separately in each half cycle.
- When OFF, the output across a series resistor is zero.
- With a 0.6 V or 0.7 V drop, the output peak falls by that drop.
- A diode across the output, in series with a battery V, clips the wave at about V.
- Two opposite diodes clip both halves.
- Capacitor branch in steady state: no current, so treat it as an open circuit.
- Find the time constant with the path the discharge really takes: τ = RpathC.
- A reverse-biased diode blocks that path.
Rectifiers & Filters
A diode passes only one half of a.c., so the output is one-way but pulsating. A filter and a regulator then smooth it to steady d.c.
27.6.1 One diode
- Positive half cycle: diode ON, output appears.
- Negative half cycle: diode OFF, no output.
- Output frequency = input frequency, f.
- Output pulses per second = N for N Hz input.
27.6.2 Centre-tap, two diodes
- Positive half: D1 ON, D2 OFF. Negative half: D2 ON, D1 OFF.
- Current through the load is in the same direction both times.
- Output frequency = 2f. For 50 Hz mains the ripple is 100 Hz.
- Each diode gets half the secondary voltage.
27.6.3 Four diodes, no centre tap
- In each half cycle, two diodes in series conduct and two are OFF.
- Output is the same as full-wave, at 2f.
27.6.4 Half-wave and full-wave
| Half-wave | Full-wave | |
|---|---|---|
| Diodes | 1 | 2 (bridge: 4) |
| Output frequency | f | 2f |
| Ripple factor | 1.21 | 0.48 |
| Max efficiency | 40.6% | 81.2% |
| PIV | V0 | 2V0 (bridge: V0) |
- ηfull = 2ηhalf.
- PIV is the largest reverse voltage a diode must bear.
27.6.5 Removing the ripple
- A capacitor goes in parallel with the load. It charges at the peaks and discharges in between.
- A choke (inductor) goes in series with the load.
- A π-filter gives the best ripple control.
- The capacitor removes the a.c. ripple, not the diodes or the transformer.
27.6.6 Order of the blocks
- Correct order: rectifier, then filter, then voltage regulator.
Zener Diode
A heavily doped diode made to work in reverse breakdown. Its voltage stays fixed at VZ while its current changes, so it steadies a supply.
27.7.1 Structure and working
- Both p and n are heavily doped, so the depletion layer is narrow.
- The narrow layer gets a very strong field, about 5 × 106 V m−1.
- That field pulls electrons out of bonds: Zener breakdown.
- It is not damaged unless its power rating is crossed.
- In forward bias, it acts as an ordinary diode.
27.7.2 How it is connected
- Connected in reverse bias and in parallel with the load.
- Series resistor R takes up the extra voltage.
- If Vin rises, IZ rises, the drop across R rises, and VL stays at VZ.
27.7.3 Standard route
- Check first: without the Zener, is the voltage across RL more than VZ?
- If not, the Zener stays OFF, IZ = 0, and it is a plain potential divider.
27.7.4 Safe limits
- Take the highest input voltage when finding the minimum R.
- Power in the Zener = VZIZ.
LED, Photodiode & Solar Cell
The LED turns current into light in forward bias. The photodiode (reverse bias) and solar cell (no bias) turn light into current.
27.8.1 Light emitting diode
- A heavily doped p-n junction, always used in forward bias.
- Electrons and holes recombine and release energy as photons.
- Photon energy is equal to or slightly less than Eg.
- Visible light needs Eg from about 1.8 eV to 3 eV.
| Material | Light |
|---|---|
| GaAs, AlGaAs | infrared |
| GaAsP | red, orange, yellow |
| GaP | green |
| ZnSe, GaN | blue |
- Advantages: low voltage, low power, long life, fast switching.
- Brightness can be controlled by the current, and colours do not fade.
- Intensity rises with current up to a limit, then falls.
- To protect an LED, use a series resistor.
27.8.2 Light detector
- Used in reverse bias. Light with hν ≥ Eg makes electron-hole pairs.
- Reverse current depends on light intensity.
- Why reverse? The fractional change in minority carriers is large, so the change in current is easy to measure.
- Reverse current rises with intensity, due to the extra minority carriers.
- Only λ < λmax can be detected.
- Eg = 2.8 eV: λmax ≈ 4430 Å. So 4000 Å is detected, but 6000 Å is not.
27.8.3 Photovoltaic device
- No external bias. It generates emf when light falls on it.
- Three steps: generation of pairs, separation by the junction field, collection.
- Band gap should be between 1.0 eV and 1.8 eV.
- Top layer (p) is thin, so that light reaches the junction.
27.8.4 Reading the graph
| Device | Bias | I-V clue | Use |
|---|---|---|---|
| Rectifier diode | forward | 1st quadrant knee | rectifier |
| Zener | reverse | 3rd quadrant, vertical | regulator |
| LED | forward | 1st, by colour | light source |
| Photodiode | reverse | 3rd, by intensity | light detector |
| Solar cell | none | 4th quadrant | electric power |
Corner
- Reverse current depends on intensity, and hardly on the reverse voltage.
- It saturates at a small reverse voltage.
Transistor Structure & Current Relations
Two p-n junctions back to back. A small base current controls a large collector current: IE = IB + IC.
27.9.1 Three regions
| Region | Size | Doping | Job |
|---|---|---|---|
| Emitter | moderate | heavy | supplies carriers |
| Base | thinnest | light | passes them on |
| Collector | largest | moderate | collects them |
- Heavily doped: emitter. Lightly doped: base.
- Two diodes back to back: npn has both arrows pointing away from the base.
- But two separate diodes cannot act as a transistor, because the base must be thin.
27.9.2 Biasing for amplification
- Emitter-base junction: forward biased.
- Collector-base junction: reverse biased.
- npn conducts with collector + and emitter − with respect to the base.
| Mode | E-B | C-B | Acts as |
|---|---|---|---|
| Active | forward | reverse | amplifier |
| Saturation | forward | forward | closed switch |
| Cut-off | reverse | reverse | open switch |
27.9.3 Where the carriers go
- npn: emitter injects electrons into the base. pnp: emitter injects holes into the base.
- Those are minority carriers in the base.
- Base is thin and lightly doped, so few recombine.
- Most pass on to the collector.
- If x% of electrons reach the collector: IC = x% of IE.
- Number of electrons per second × e = current.
27.9.4 α and β
- α is slightly less than 1, usually 0.95 to 0.99.
- β is large, usually 20 to 200.
- For small changes: βac = ΔIC ÷ ΔIB, at constant VCE.
27.9.5 Convert one into the other
| α | 0.95 | 0.96 | 0.98 | 0.99 |
|---|---|---|---|---|
| β | 19 | 24 | 49 | 99 |
- Given β and IE: IC = αIE = [β ÷ (1 + β)] IE.
- Collector voltage drop gives IC = VR ÷ RC, and then IB = IC ÷ β.
CE Amplifier, Switch & Oscillator
In common emitter mode a small input signal gives a large output, 180° out of phase. Voltage gain is βRL ÷ Ri.
27.10.1 Circuit and action
- Input is between base and emitter. Output is between collector and emitter.
- Base-emitter junction forward biased, collector-base reverse biased.
- Operated in the active region.
- Input impedance is low and output impedance is high.
- When IB rises, IC rises and VCE falls. That is the 180° phase reversal.
- An output signal for Vi = V0 cos(ωt) is AVV0 cos(ωt + π).
27.10.2 Three formulas to know
- Ratio: APAV = β.
- Output voltage: Vo = AVVi.
- Base current: Ib = Vi ÷ Ri. Collector current: Ic = βIb.
- Using AV and impedances: AP = AV2 Ri ÷ Ro.
27.10.3 CB, CE, CC
| CB | CE | CC | |
|---|---|---|---|
| Current gain | α < 1 | β, high | high |
| Voltage gain | medium | high | below 1 |
| Power gain | medium | highest | low |
| Phase | 0° | 180° | 0° |
- Common base: output in phase with the input.
- CE is most used: it gives the highest power gain.
27.10.4 CE graphs
- Input resistance is about 1 kΩ. Output resistance is much larger.
27.10.5 Cut-off and saturation
- Switch: cut-off (OFF) and saturation (ON).
- Amplifier: the straight active region.
27.10.6 a.c. with no input
- It generates a.c. with no external input, using a tank circuit, amplifier and positive feedback.
- Part of the output power returns to the input in phase.
- Condition: if a fraction k of output feeds back, then kAV = 1.
- Damped LC swings are kept steady by this feedback, giving a constant-amplitude wave.
Corner
- Read ΔIC between two IB curves at the same VCE.
- Output resistance ro = (ΔVCEΔIC) at fixed IB; it is large.
- Input resistance ri = (ΔVBEΔIB) at fixed VCE; it is small.
- Input loop: VBB = IBRB + VBE.
- Output loop: VCC = ICRC + VCE.
- Saturation starts when VCE ≈ 0, so IC ≈ VCC ÷ RC.
- Base-emitter and base-collector each act as a diode.
- npn: low resistance with + on the base. pnp: low resistance with − on the base.
- No conduction between C and E in either direction.
Basic Gates, NAND, NOR, XOR
A logic gate has one output for its digital inputs. Three basics, OR, AND and NOT, build all the others. Learn the one master truth table below.
27.11.1 Two states only
- 1 = high, on, true. 0 = low, off, false.
- Boolean algebra uses three operations: OR (+), AND (·), NOT (bar).
27.11.2 OR, AND, NOT
- OR: output 1 if either or both inputs are 1.
- AND: output 1 only if all inputs are 1.
- NOT: output is the opposite of the input.
27.11.3 NAND, NOR, XOR, XNOR
27.11.4 Master table
| A | B | OR | AND | NAND | NOR | XOR | XNOR |
|---|---|---|---|---|---|---|---|
| 0 | 0 | 0 | 0 | 1 | 1 | 0 | 1 |
| 0 | 1 | 1 | 0 | 1 | 0 | 1 | 0 |
| 1 | 0 | 1 | 0 | 1 | 0 | 1 | 0 |
| 1 | 1 | 1 | 1 | 0 | 0 | 0 | 1 |
- NAND: 0 only when all inputs are 1.
- NOR: 1 only when all inputs are 0.
- XOR: 1 when inputs are different; 1 for an odd number of 1s.
- XNOR: 1 when inputs are the same.
27.11.5 Two clues give the gate
| Clue | Gate |
|---|---|
| (0, 0) gives 1 and (1, 0) gives 1 | NAND |
| (0, 0) gives 1 and (1, 0) gives 0 | NOR |
| (1, 0) gives 1 and (0, 0) gives 0 | OR or XOR |
| (1, 1) gives 0 and (1, 0) gives 1 | NAND or XOR |
27.11.6 Two inputs joined
- NAND with A = B gives NOT.
- NOR with A = B gives NOT.
- AND or OR with A = B just gives A.
27.11.7 NOT at the output
| Combination | Result |
|---|---|
| AND then NOT | NAND |
| OR then NOT | NOR |
| NAND then NOT | AND |
| NOR then NOT | OR |
| XOR then NOT | XNOR |
27.11.8 For simplifying
| Rule | Result |
|---|---|
| A + 0, A + 1 | A, 1 |
| A · 0, A · 1 | 0, A |
| A + A, A · A | A, A |
| A + A, A · A | 1, 0 |
| A + AB | A |
| A + AB | A + B |
- These two are De Morgan’s theorems. A double bar cancels.
Gate Circuits & Boolean Output
Label the output of every gate from left to right, then simplify with De Morgan. This is the most asked idea of the chapter.
27.12.1 Finding Y for given inputs
- Write the inputs on the circuit.
- Find each gate’s output in turn, from left to right.
- Write the value on each wire. Never skip a gate.
27.12.2 Which gate is it equivalent to?
- Try all four inputs: (0, 0), (0, 1), (1, 0), (1, 1).
- Build the Y column.
- Match it with the master truth table.
| Y column | Gate |
|---|---|
| 0 1 1 1 | OR |
| 0 0 0 1 | AND |
| 1 1 1 0 | NAND |
| 1 0 0 0 | NOR |
| 0 1 1 0 | XOR |
| 1 0 0 1 | XNOR |
27.12.3 Boolean expression
- Write the expression at each gate, using A, B and bars.
- Break long bars with De Morgan’s theorems.
- Simplify using the rules of Concept 11.
27.12.4 NAND alone can build everything
| Build | NAND circuit | Result |
|---|---|---|
| NOT | one, inputs joined | A |
| AND | NAND then NOT | A · B |
| OR | NOT each input, then NAND | A + B |
- NOR is the other universal gate.
| Build | NOR circuit | Result |
|---|---|---|
| NOT | one, inputs joined | A |
| OR | NOR then NOT | A + B |
| AND | NOT each input, then NOR | A · B |
- Output of AND into NOT, or a bubble at a gate’s input, means the signal is inverted.
- NOT each input, then AND: A · B = A + B, so it is a NOR gate.
- NOT each input, then OR: A + B = A · B, so it is a NAND gate.
27.12.5 From basic gates
27.12.6 Find G from the truth table
- Find the two inputs arriving at G from the truth table rows.
- Write them beside the required Y.
- Match that small table with the master table.
Corner
- Split the time axis wherever A or B changes.
- Read A and B in each slot and use the truth table.
- Draw Y slot by slot.
- Number of rows in a truth table = 2n.
- XOR of many inputs is 1 when an odd number of inputs are 1.
Just see this before the exam
Whole chapter on one page
Eg: Si 1.1, Ge 0.7 eV
insulator > 3 eV
λmax = 1240 ÷ Eg nm
0 K: pure Si is an insulator
n-type: P, As, Sb
p-type: B, Al, In
nenh = ni2
Both stay neutral
semiconductor: R falls
metal: R rises
σ = e(neμe + nhμh)
μe > μh
forward: thin, low R
reverse: wide, high R
VB: Si 0.7, Ge 0.3 V
E = VB ÷ d
half: f, full: 2f
η: 40.6%, 81.2%
ripple: 1.21, 0.48
Vdc = V0 ÷ π, 2V0 ÷ π
reverse, parallel to load
I = (Vin − VZ) ÷ R
IZ = I − IL
IZ(max) = P ÷ VZ
LED: forward
photodiode: reverse
solar cell: no bias, 4th quad.
solar Eg: 1.0 to 1.8 eV
IE = IB + IC
α = IC ÷ IE, β = IC ÷ IB
AV = βRL ÷ Ri
AP = βAV, phase 180°
NAND: 1 1 1 0
NOR: 1 0 0 0
XOR: 0 1 1 0
Universal: NAND, NOR
Avoid these = easy marks
n-type crystal is negative
Depletion widens in forward bias
Zener in forward bias, in series
Output of CE amplifier is in phase
n-type and p-type are neutral
Forward thins it; reverse widens it
Reverse bias, parallel with the load
It is 180° out of phase